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टेलीग्राम चैनल का लोगो jeemainguru — JEEMAIN.GURU| JEE materials download
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नवीनतम संदेश

2022-04-14 13:31:17 Comment
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351 views10:31
ओपन / कमेंट
2022-03-16 07:14:26 Mathematics handwritten one page Revision notes

Most important ( written by jee Topper)
7.0K viewsedited  04:14
ओपन / कमेंट
2022-02-04 08:02:45 Notes on Chemical Bonding
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Chemical bond:-

Chemical bond is the attractive force which holds various constituents together in a molecule.

There are three types of chemical bonds: Ionic Bond, Covalent Bond, Co-ordinate Bond.

Octet Rule:

Atoms form chemical bonds in order to complete their octet i.e. eight electrons in their valence shell.

Lewis Structures:

Pair of bonded electrons is by means of a ‘dash’ (-) usually called a ‘bond’.

Lone pairs or ‘non-bonded’ electrons are represented by ‘dots’.

Electrons present in the last shell of atoms are called valence electrons.

Exceptions to the Octet Rule:

Species with odd number of electrons: NO, NO2,

Incomplete octet for the central atom: LiCl, BeH2 and BCl3

Expanded octet for the central atom: PF5, SF6 and H2SO4

Formal Charge:

Formal charge is the difference between the number of valence electrons in an isolated atom and number of electrons assigned to that atoms in Lewis structure.

Formal charge = [Total number of valence electrons in the free atom ) - (Total number of lone pairs of electrons) -1/2(Total number of shared electrons i.e. bonding electrons)]

Resonance:

For molecules and ions showing resonance it is not possible to draw a single Lewis structure.

All the properties of such species can only be explained by two or more Lewis structures. Example: Resonance of O3

Ionic Bonding:

Formation of Ionic Bond:
Formation of ionic bond takes place between a metal and a non-metal by transfer of electron.

Formation of gaseous cations

A(g) + I.E. → A+ (g) + e

Ionization Energy

Formation of gaseous anions

X(g) + e → X- (g) + E.A

Electron Affinity

Packing of ions of opposite charges to form ionic solids

A+ (g) + X- (g) →AX (s) +Energy

Lattice energy

Conditions required of formation of ionic bonds:

Low I.E of cation.

High E.A of anion.

High lattice energy.

Covalent Bonding:

Covalent bond is formed between two non-metals by sharing of electrons.

Electron pairs which participate in bonding are called bond pairs.

Electron pairs which do not participate in bonding are called lone pairs.

There could be single, double or triple covalent bonds between two elements depending on the number of electrons being shared.

VSEPR (Valence Shell Electron Pair Repulsion) Theory:

The shape of the molecule is determined by repulsions between all of the electron pairs present in the valence shell.

Order of the repulsion: Lone pair.Lone pair > Lone pair. Bond pair > Bond pair. Bond pair.

Repulsion among the bond pairs is directly proportional to the bond order and electronegativity difference between the central atom and the other atoms.
1.1K views05:02
ओपन / कमेंट
2021-12-17 08:58:06

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2021-12-16 15:51:19 JEEMAIN.GURU| JEE materials download pinned a photo
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ओपन / कमेंट
2021-12-16 15:50:40
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738 views12:50
ओपन / कमेंट
2021-11-26 14:52:55 #jee #math

Differential Calculus: Notes on Maxima and Minima

Local Maximum: A function f(x) is said to have a local maximum at x = a if the value of f(a) is greater than all the values of f(x) in a small neighbourhood of x = a. Mathematically, f (a) > f (a – h) and f (a) > f (a + h) where h > 0, then a is called the point of local maximum.


Local Minimum: A function f(x) is said to have a local minimum at x = a, if the value of the function at x = a is less than the value of the function at the neighboring points of x = a. Mathematically, f (a) < f (a – h) and f (a) < f (a + h) where h > 0, then a is called the point of local minimum.


A point of local maximum or a local minimum is also called a point of local extremum.

A point where the graph of function is continuous and has a tangent line and where the concavity changes is called point of inflexion.

At the point of inflexion, either y” = 0 and changes sign or y” fails to exist.

At the point of inflexion, the curve crosses its tangent at that point.

A function cannot have point of inflexion and extrema at the same point.

Working rules to find points of local maxima and local minima:

1. First Derivative Test:

If f'(a) = 0 and f'(x) changes its sign while passing through the point x = a, then

f(x) would have a local maximum at x = a if f'(a – 0) > 0 and f'(a + 0) < 0. It means that f'(x) should change its sign from positive to negative.

f(x) would have local minimum at x = a if f'(a – 0) < 0 and f'(a + 0) > 0 . It means that f'(x) should change its sign from negative to positive.

If f(x) doesn’t change its sign while passing through x = a, then f (x) would have neither a maximum nor minimum at x = a. e.g. f (x) = x3 doesn’t have any local maxima or minima at x = 0.

2. Second Derivative Test:

Let f(x) be a differentiable function on a given interval and let f'' be continuous at stationary point. Find f'(x) and solve the equation f'(x) = 0 given let x = a, b, … be solutions.

There can be two cases:

Case (i): If f''(a) <0 then f(a) is maximum.

Case (ii): If f ''(a) > 0 then f(a) is minimum.

In case, f''(a) = 0 the second derivatives test fails and then one has to go back and apply the first derivative test.

If f''(a) = 0 and a is neither a point of local maximum nor local minimum then a is a point of inflection.

3. nth Derivative Test for Maxima and Minima: Also termed as the generalization of the second derivative test, it states that if the n derivatives i.e. f '(a) = f''(a) = f'''(a) =………. = f n(a) = 0 and fn+1(a) ≠ 0 (all derivatives of the function up to order ‘n’ vanish and (n + 1)th order derivative does not vanish at x = a), then f (x) would have a local maximum or minimum at x = a iff n is odd natural number and that x = a would be a point of local maxima if fn+1 (a) < 0 and would be a point of local minima if fn+1 (a) > 0.

In some questions involving determination of maxima and minima, it might become difficult to decide whether f(x) actually changes its sign while passing through x = a and here, nth derivative test can be applied.

Global Minima & Maxima of f(x) in [a, b] is the least or the greatest value of the function f(x) in interval [a, b].

1. The function f(x) has a global maximum at the point ‘a’ in the interval I if f (a) ≥ f(x), for all x ∈ I.

2. Function f(x) has a global minimum at the point ‘a’ if f (a) ≤ f (x), for all x ∈ I.

Global Maxima Minima always occur either at the critical points of f(x) within [a, b] or at the end points of the interval.

Computation of Global Maxima and minima in maxima minima problems:

1. Compute the critical points of f(x) in (a, b). Let the various critical points be C1, C2, …. , Cn.

2. Next, compute the value of the function at these critical points along with the end points of the domain. Let us denote these values by f(C1), f(C2)………..f(Cn).

3. Now, compute M* = max{f(a), f(C1), f(C2)………..f(Cn), f(b)} and M = min{f(a), f(C1), f(C2)………..f(Cn), f(b)}.Now M* is the maximum value of f(x) in [a, b] and M is the minimum value of f(x) in [a, b].
745 views11:52
ओपन / कमेंट
2021-11-15 19:55:52 https://jeemain.guru/download-ncert-books-for-class12-maths-pdf-2022-23/
1.8K views16:55
ओपन / कमेंट
2021-11-10 20:03:07 Green Algae :- Chlorophyceae

Brown algae :- Phaeophyceae

Red algae :- Rhodophyceae


Dominant pigments

Chlorophyceae :- Chlorophyll a and b

Phaeophyceae :- Chlorophyll a and c

Rhodophyceae :- Chlorophyll a and d


Reserved food material

Chlorophyceae : - Starch, Proteins, Oil droplets

Phaeophyceae : - Laminarian starch and Mannitol

Rhodophyceae : - Floridian starch similar to Amylopectin and Glycogen
1.0K views17:03
ओपन / कमेंट