Comparison Between Sigma And Pi Bond : Sigma Bond 1. Forme | L.N.V NEET JEE DPPs™

Comparison Between Sigma And Pi Bond :

Sigma Bond

1. Formed by axial overlapping
2. Involves s-s, s-p, p-p (axial) & hybrid orbitals
3. Extent of overlapping is more so stronger
4. Free rotation around s bond is possible
5. Hybridized or unhybridized orbital forms s bond
6. Independent existence of s-bond.

Pi Bond

1. Formed by side by side overlapping
2. Involve p-p, p-d & d-d orbital
3. Extent of overlapping is less so weaker
4. Free rotation around p bond is not possible
5. Hybridized orbital never forms pi bond
6. No independent existence.

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